Neutron scattering, the irregular dispersal of free neutrons by matter, can refer to either the naturally occurring physical process itself or to the man-made experimental techniques that use the natural process for investigating materials. The natural/physical phenomenon is of elemental importance in nuclear engineering and the nuclear sciences. Regarding the experimental technique, understanding and manipulating neutron scattering is fundamental to the applications used in crystallography, physics, physical chemistry, biophysics, and materials research.
Neutron scattering is practiced at research reactors and spallation neutron sources that provide neutron radiation of varying intensities. Neutron diffraction (elastic scattering) techniques are used for analyzing structures; where inelastic neutron scattering is used in studying atomic vibrations and other excitations.
Scattering of fast neutrons
See also: Neutron temperature and neutron moderator "Fast neutrons" (see neutron temperature) have a kinetic energy above 1 MeV. They can be scattered by condensed matter—nuclei having kinetic energies far below 1 eV—as a valid experimental approximation of an elastic collision with a particle at rest. With each collision, the fast neutron transfers a significant part of its kinetic energy to the scattering nucleus (condensed matter), the more so the lighter the nucleus. And with each collision, the "fast" neutron is slowed until it reaches thermal equilibrium with the material in which it is scattered. Neutron moderators are used to produce thermal neutrons, which have kinetic energies below 1 eV (T < 500K). Thermal neutrons are used to maintain a nuclear chain reaction in a nuclear reactor, and as a research tool in neutron scattering experiments and other applications of neutron science (see below). The remainder of this article concentrates on the scattering of thermal neutrons.
Neutron-matter interaction
Because neutrons are electrically neutral, they penetrate more deeply into matter than electrically charged particles of comparable kinetic energy, and thus are valuable as probes of bulk properties. Neutrons interact with atomic nuclei and with magnetic fields from unpaired electrons, causing pronounced interference and energy transfer effects in neutron scattering experiments. Unlike an x-ray photon with a similar wavelength, which interacts with the electron cloud surrounding the nucleus, neutrons interact primarily with the nucleus itself, as described by Fermi's pseudopotential. Neutron scattering and absorption cross sections vary widely from isotope to isotope. Neutron scattering can be incoherent or coherent, also depending on isotope. Among all isotopes, hydrogen has the highest scattering cross section. Important elements like carbon and oxygen are quite visible in neutron scattering—this is in marked contrast to X-ray scattering where cross sections systematically increase with atomic number. Thus neutrons can be used to analyze materials with low atomic numbers, including proteins and surfactants. This can be done at synchrotron sources but very high intensities are needed, which may cause the structures to change. The nucleus provides a very short range, as isotropic potential varies randomly from isotope to isotope, which makes it possible to tune the (scattering) contrast to suit the experiment. Scattering almost always presents both elastic and inelastic components. The fraction of elastic scattering is determined by the Debye-Waller factor or the Mössbauer-Lamb factor. Depending on the research question, most measurements concentrate on either elastic or inelastic scattering. Achieving a precise velocity, i.e. a precise energy and de Broglie wavelength, of a neutron beam is important. Such single-energy beams are termed 'monochromatic', and monochromaticity is achieved either with a crystal monochromator or with a time of flight (TOF) spectrometer. In the time-of-flight technique, neutrons are sent through a sequence of two rotating slits such that only neutrons of a particular velocity are selected. Spallation sources have been developed that can create a rapid pulse of neutrons. The pulse contains neutrons of many different velocities or de Broglie wavelengths, but separate velocities of the scattered neutrons can be determined afterwards by measuring the time of flight of the neutrons between the sample and neutron detector.
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